Cambridge IGCSE0620

Water

Chemistry 0620 Chapter Notes

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1. The Air We Breathe: Composition and Importance

Clean, dry air is not a single substance but a mixture of several gases. The vast majority, about 99%, is made up of two elements: nitrogen (approximately 78%) and oxygen (approximately 21%). The remaining 1% consists of other gases, including argon (about 0.9%), carbon dioxide (about 0.04%), and small amounts of other noble gases like neon and helium. Oxygen is the most critical component for life as we know it. It is essential for aerobic respiration, the chemical process in our cells that releases energy from the food we eat (like glucose) to power all life processes.

C₆H₁₂O₆ (aq) + 6O₂ (g) → 6CO₂ (g) + 6H₂O (l) + Energy

Key term

Mixture: Two or more substances that are mixed together but are not chemically combined.

Examiner insight

Examiners expect you to know the approximate percentages of nitrogen and oxygen and to be clear that air is a mixture, meaning its components can be separated by physical means.

Fun fact

If you could separate all the argon from the air in an average-sized room, you would have enough to fill about 20 party balloons.

Worked example 12 marks

A student is asked to list the main components of clean, dry air. Name the two most abundant gases and state their approximate percentage composition.

  1. 1

    Step 1: Identify the most abundant gas in the air. This is Nitrogen.

  2. 2

    Step 2: State the approximate percentage of Nitrogen. This is 78%.

  3. 3

    Step 3: Identify the second most abundant gas. This is Oxygen.

  4. 4

    Step 4: State the approximate percentage of Oxygen. This is 21%.

Recap

  • Dry air is a mixture of gases.
  • Nitrogen makes up approximately 78% of the air.
  • Oxygen makes up approximately 21% of the air.
  • Argon and carbon dioxide make up most of the remaining 1%.
  • Oxygen is essential for aerobic respiration in living organisms.

Quick check

  1. Besides nitrogen and oxygen, name one other gaseous element found in the air.1 mark
  2. What is the name of the process in living cells that uses oxygen to release energy?1 mark

2. Measuring the Percentage of Oxygen in Air

A common experiment to determine the percentage of oxygen in the air involves reacting a known volume of air with a substance that removes the oxygen. One method uses damp iron filings in an inverted measuring cylinder or test tube placed in a beaker of water. The iron reacts with the oxygen in the trapped air, forming rust. As the oxygen is used up, water is drawn up into the measuring cylinder to fill the space. The initial volume of air is recorded, and the final volume of the remaining gas is measured after the reaction stops. The decrease in volume corresponds to the volume of oxygen used. The percentage of oxygen can then be calculated as (change in volume / initial volume of air) × 100.

Percentage of oxygen = (Volume of oxygen used / Initial volume of air) × 100

4Fe(s) + 3O₂(g) → 2Fe₂O₃(s) (A simplified equation for rusting)

Key term

Oxidation: A chemical reaction that involves the loss of electrons or gain of oxygen.

Common pitfall

A common mistake is forgetting to use the initial volume of air in the calculation, or not allowing the apparatus to return to room temperature before taking the final reading, which leads to an inaccurate volume measurement due to gas expansion.

Worked example 13 marks

In an experiment, 50 cm³ of air was passed over heated copper. The volume of gas remaining at the end was 39.5 cm³. Calculate the percentage of oxygen in the air sample.

  1. 1

    Step 1: Calculate the volume of oxygen that reacted. This is the change in volume. Volume of oxygen = Initial volume of air - Final volume of gas.

  2. 2

    Volume of oxygen = 50 cm³ - 39.5 cm³ = 10.5 cm³.

  3. 3

    Step 2: Calculate the percentage of oxygen using the formula. Percentage of oxygen = (Volume of oxygen / Initial volume of air) × 100.

  4. 4

    Percentage of oxygen = (10.5 cm³ / 50 cm³) × 100 = 21%.

  5. 5

    Answer: The percentage of oxygen in the air is 21%.

Recap

  • The percentage of oxygen in air can be found by removing oxygen from a fixed volume of air.
  • Damp iron filings or heated copper can be used to react with and remove oxygen.
  • The volume of the air decreases as oxygen is used up.
  • The percentage is calculated from the change in volume compared to the initial volume.
  • The apparatus must be left to cool before taking the final volume reading if heat is used.

Quick check

  1. In the experiment using iron filings, why must the iron be damp?1 mark

3. Air Pollution: Sources and Effects

Air pollutants are harmful substances released into the atmosphere. Most are by-products of burning fossil fuels (coal, oil, and natural gas). Key pollutants include:

  1. Carbon Monoxide (CO): A toxic gas produced during the incomplete combustion of carbon-containing fuels, such as in car engines with an insufficient oxygen supply. It reduces the ability of blood to transport oxygen.
  2. Sulfur Dioxide (SO₂): Produced when fossil fuels containing sulfur impurities (especially coal) are burned in power stations and factories. It dissolves in rainwater to form acid rain, which damages buildings, forests, and aquatic life. It also causes respiratory problems.
  3. Oxides of Nitrogen (NOx): Formed at the high temperatures inside car engines and power station furnaces, where nitrogen and oxygen from the air react. Like SO₂, they contribute to acid rain and cause respiratory issues.

S(s) + O₂(g) → SO₂(g)

N₂(g) + O₂(g) → 2NO(g)

Key term

Incomplete Combustion: The burning of a substance in a limited supply of oxygen, which produces carbon monoxide and/or soot instead of carbon dioxide.

Examiner insight

For full marks on questions about pollution, you must clearly and specifically link a named pollutant to its source and a distinct harmful effect.

Worked example 12 marks

Acid rain is a significant environmental problem. Name one pollutant gas responsible for acid rain and state its primary man-made source.

  1. 1

    Step 1: Identify a pollutant gas that causes acid rain. Either Sulfur Dioxide or Oxides of Nitrogen is a correct answer.

  2. 2

    Named pollutant: Sulfur Dioxide (SO₂).

  3. 3

    Step 2: State the main source of this pollutant. Sulfur dioxide is primarily produced from the combustion of fossil fuels, particularly coal in power stations.

  4. 4

    Source: Burning coal in power stations.

Recap

  • Air pollutants are harmful substances in the air, often from burning fossil fuels.
  • Carbon monoxide (CO) from incomplete combustion is poisonous.
  • Sulfur dioxide (SO₂) from burning sulfur-containing fuels causes acid rain.
  • Oxides of nitrogen (NOx) from high-temperature combustion (e.g., car engines) also cause acid rain.
  • Acid rain damages buildings, kills trees, and harms aquatic ecosystems.

Quick check

  1. Why is carbon monoxide dangerous to humans?1 mark

4. The Chemistry of Rusting

Rusting is the specific name for the corrosion of iron and its alloys, like steel. It is a chemical process that converts iron into hydrated iron(III) oxide, which is the familiar reddish-brown, flaky substance we call rust. For rusting to occur, two substances must be present: oxygen (usually from the air) and water. Rusting is an oxidation reaction where iron loses electrons. The process can be accelerated by the presence of salt (which is why cars rust faster in winter when roads are salted) or by acidic conditions.

4Fe(s) + 3O₂(g) + 2nH₂O(l) → 2Fe₂O₃·nH₂O(s)

Key term

Rust: The common name for hydrated iron(III) oxide, the reddish-brown substance formed by the corrosion of iron.

Common pitfall

A very common error is to state that only water or only oxygen is needed for rusting. Candidates must remember that both are essential for the reaction to happen.

Worked example 13 marks

An experiment is set up with four test tubes containing an iron nail under different conditions: A: Nail in dry air. B: Nail in boiled water with a layer of oil on top. C: Nail in tap water. D: Nail in anhydrous calcium chloride. In which test tube would the nail rust? Explain your answer.

  1. 1

    Step 1: Analyze the conditions in each tube. Tube A has oxygen but no water. Tube B has water but no oxygen (boiled to remove it, oil prevents it re-entering). Tube D has a drying agent, so no water.

  2. 2

    Step 2: Identify the tube with both required conditions. Tube C has the nail exposed to both tap water and air (oxygen dissolved in the water and in the tube).

  3. 3

    Step 3: State the conclusion and explanation. The nail in test tube C would rust.

  4. 4

    Explanation: Rusting requires the presence of both oxygen and water. Only test tube C provides both of these conditions.

Recap

  • Rusting is the corrosion of iron or steel.
  • The chemical name for rust is hydrated iron(III) oxide.
  • Both oxygen and water are essential for rusting to occur.
  • Salt and acid can speed up the rusting process.
  • Rusting is an oxidation reaction.

Quick check

  1. State the two conditions required for an iron nail to rust.2 marks

5. Investigating and Preventing Rust

Since rusting requires oxygen and water, prevention methods focus on keeping one or both of these away from the iron surface. This is achieved in several ways:

  1. Barrier Methods: Creating a physical barrier between the iron and the environment. Examples include painting (for car bodies, gates), oiling or greasing (for engine parts, bike chains), and coating with plastic (for wire fencing, dish racks).
  2. Sacrificial Protection: This involves using a more reactive metal to protect the iron. Zinc is more reactive than iron, so if a piece of iron is coated in zinc (a process called galvanising), the zinc will react and corrode first, 'sacrificing' itself to protect the iron. This method is used for roofing sheets and ship hulls.
  3. Alloying: Iron can be mixed with other elements like chromium and nickel to create stainless steel, an alloy that is highly resistant to rusting.

Zn(s) → Zn²⁺(aq) + 2e⁻ (Shows the more reactive zinc atom losing electrons instead of iron)

Key term

Galvanising: The process of applying a protective coating of zinc to iron or steel to prevent rusting.

Worked example 14 marks

A steel bicycle is left outside in the rain. Suggest two different methods that are used to prevent parts of the bicycle from rusting, and for each method, name a part it would protect.

  1. 1

    Method 1: Painting. This creates a barrier to keep out oxygen and water. It is used to protect the bicycle frame.

  2. 2

    Method 2: Oiling/Greasing. This also acts as a waterproof barrier. It is used to protect the moving parts, such as the chain and gears.

Worked example 23 marks

Explain why attaching a block of magnesium to the steel hull of a ship prevents the hull from rusting.

  1. 1

    Step 1: State the principle. This is an example of sacrificial protection.

  2. 2

    Step 2: Compare the reactivity of the metals. Magnesium is more reactive than iron (which is the main component of steel).

  3. 3

    Step 3: Explain the process. Because it is more reactive, the magnesium block will corrode (oxidise) in preference to the steel hull. The magnesium is 'sacrificed' to protect the iron.

Recap

  • Rust prevention involves blocking oxygen and/or water from reaching the iron.
  • Barrier methods include painting, oiling, and plastic coating.
  • Sacrificial protection uses a more reactive metal, like zinc, to corrode instead of the iron.
  • Galvanising is the process of coating iron with zinc.
  • Alloying iron with chromium creates rust-resistant stainless steel.

Quick check

  1. Name the method of rust prevention where iron is coated with zinc.1 mark

6. From Reservoir to Tap: Water Treatment

Water from rivers and reservoirs is not safe to drink directly. It must be treated to remove impurities and harmful microbes. The process typically involves several stages:

  1. Screening: Water passes through large screens to remove large debris like leaves, branches, and plastic bags.
  2. Coagulation and Flocculation: A chemical coagulant, such as aluminium sulfate, is added. This causes tiny suspended particles like clay and silt to stick together, forming larger, heavier clumps called 'floc'.
  3. Sedimentation: The water is kept in large, still tanks. The heavy floc particles sink to the bottom as sediment, which is later removed.
  4. Filtration: The water is then passed through layers of sand and gravel. These filter beds remove any remaining fine suspended particles.
  5. Chlorination: A small, controlled amount of chlorine gas or a chlorine compound is added to the water. This is a crucial step that kills bacteria and other harmful microorganisms, making the water safe to drink (potable).

Key term

Potable Water: Water that has been treated and is safe for human consumption.

Examiner insight

Be prepared to describe the main stages of water treatment in the correct order and, most importantly, to explain the function of each stage.

Fun fact

The ancient Romans were masters of water engineering, but they didn't know about microbes. They believed the 'cleanest' water was that which came from the purest source, not realising the invisible dangers it could hold.

Worked example 14 marks

During water treatment, the water is passed through sand and gravel filters, and then chlorine is added. Explain the purpose of each of these two stages.

  1. 1

    Step 1: Explain the purpose of filtration. The sand and gravel filters are used to remove small, insoluble particles that did not settle out during sedimentation.

  2. 2

    Step 2: Explain the purpose of chlorination. Chlorine is added to kill harmful microorganisms, such as bacteria and viruses, which are too small to be removed by filtration. This disinfects the water and makes it safe to drink.

Recap

  • Water treatment makes water from natural sources safe to drink.
  • Coagulants are used to clump together small suspended particles.
  • Filtration through sand and gravel removes insoluble solids.
  • Chlorination is the essential step for killing harmful microbes like bacteria.
  • In some areas, fluoride is also added to help prevent tooth decay.

Quick check

  1. What is the name of the process that uses chemicals like aluminium sulfate to make small particles in water clump together?1 mark
  2. Why is it necessary to add chlorine to water even after it has been filtered?1 mark

7. Testing for Water and Its Purity

In chemistry, it's important to be able to test for the presence of water and to determine if it is pure. These are two separate tests.

Test for the presence of water: This is a chemical test to confirm that water molecules (H₂O) are present. There are two common tests:

  1. Anhydrous copper(II) sulfate: This is a white powder. In the presence of water, it turns blue as it becomes hydrated.
  2. Anhydrous cobalt(II) chloride paper: This is blue paper. In the presence of water, it turns pink.

Test for purity: This is a physical test. A pure substance has sharp, fixed melting and boiling points. For water at standard atmospheric pressure:

  • The boiling point is exactly 100°C.
  • The freezing point (or melting point) is exactly 0°C.

If a sample of water contains dissolved impurities (like salt), its boiling point will be raised (above 100°C) and its freezing point will be lowered (below 0°C).

CuSO₄(s) (white) + 5H₂O(l) → CuSO₄·5H₂O(s) (blue)

CoCl₂(s) (blue) + 6H₂O(l) → CoCl₂·6H₂O(s) (pink)

Key term

Pure Substance: A substance consisting of only one element or one compound, which has distinct, fixed physical properties like melting and boiling points.

Common pitfall

Confusing the test for water's presence with the test for its purity. The chemical tests (copper sulfate, cobalt chloride) only show that water is present; they do not indicate purity.

Worked example 14 marks

A student is given a colourless, odourless liquid. Describe two tests the student must perform to prove that the liquid is pure water. State the expected results for each test.

  1. 1

    Test 1: Test for the presence of water. Add a few drops of the liquid to some white anhydrous copper(II) sulfate powder. Expected result: The white powder will turn blue.

  2. 2

    Test 2: Test for purity. Carefully heat a sample of the liquid and measure its boiling point using a thermometer. Expected result: The liquid will boil at exactly 100°C (at standard pressure).

Recap

  • To test for the presence of water, use white anhydrous copper(II) sulfate, which turns blue.
  • Alternatively, use blue cobalt(II) chloride paper, which turns pink when wet.
  • To test for the purity of water, measure its boiling and freezing points.
  • Pure water boils at 100°C and freezes at 0°C at standard pressure.
  • Impurities raise the boiling point and lower the freezing point of water.

Quick check

  1. What colour change is observed when water is added to anhydrous cobalt(II) chloride?1 mark
  2. A sample of salty water is boiled. Would its boiling point be 100°C, below 100°C, or above 100°C?1 mark

End-of-chapter exercise

Test yourself on the whole chapter. Work through these before moving on.

  1. Clean air is a mixture of gases. Name the two most abundant gases in clean, dry air and state their approximate percentage composition.2 marks
  2. State the two conditions that are essential for the rusting of an iron gate.2 marks
  3. Describe a chemical test to show that a colourless liquid contains water. State the substance used and the positive result.2 marks
  4. Explain why chlorine is added as a final step in the treatment of drinking water.2 marks
  5. A student sets up an experiment by placing a damp iron nail in a sealed test tube full of air. After one week, describe two observations the student would make inside the test tube and provide an explanation for one of them.4 marks
  6. Acid rain is caused by pollutants reacting with water in the atmosphere. Name two different pollutant gases that contribute to acid rain and state one major man-made source for each gas.4 marks
  7. A chemist wants to prove that a sample of seawater is not pure water. Describe two different experimental tests they could perform and the results they would expect to obtain.4 marks
  8. Galvanising is a method used to protect steel from rusting. Explain how coating steel with zinc provides protection, even if the coating gets scratched.3 marks
  9. Describe the main stages involved in treating river water to make it suitable for drinking. For at least two stages, state what type of impurity is removed.6 marks
  10. An experiment to measure the percentage of oxygen in the air using the rusting of iron gave a result of 18%. The accepted value is 21%. Suggest two possible reasons for this lower-than-expected result.2 marks

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