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Chemistry: Materials, elements and the Periodic Table

Science Stage 7 Chapter Notes

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Chemistry: Materials, elements and the Periodic Table
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1. Elements, Compounds and Mixtures

All matter can be classified into three main types. An 'element' is a pure substance consisting of only one type of atom, which cannot be broken down into anything simpler by chemical means (e.g., Iron, Fe). A 'compound' is a pure substance formed when two or more different elements are chemically bonded together in a fixed ratio. The properties of a compound are completely different from its constituent elements (e.g., Water, H₂O, is very different from hydrogen and oxygen). A 'mixture' consists of two or more substances (elements or compounds) that are not chemically bonded. They can be separated by physical means, and the substances in a mixture largely keep their original properties (e.g., air is a mixture of nitrogen, oxygen, and other gases).

Key term

Element: A pure substance consisting of only one type of atom, which cannot be broken down into simpler substances by chemical reactions.

Common pitfall

Confusing a compound with a mixture. Remember, making a compound is a chemical change that creates a new substance, while making a mixture is just a physical change.

Worked example 16 marks

Classify each of the following as an element, a compound, or a mixture, giving a reason for each:(a) Salt water(b) Copper(c) Carbon dioxide (CO₂)

  1. 1

    (a) Salt water is a mixture. It consists of salt (a compound) and water (a compound) that are mixed together but not chemically bonded. They can be separated by physical means like evaporation.

  2. 2

    (b) Copper is an element. It is found on the periodic table and consists of only copper atoms.

  3. 3

    (c) Carbon dioxide is a compound. It is made of carbon and oxygen atoms that are chemically bonded together in a fixed ratio (1 carbon to 2 oxygen).

Recap

  • Elements are made of one type of atom.
  • Compounds contain different elements chemically bonded in a fixed ratio.
  • Mixtures contain different substances that are not chemically bonded.
  • Compounds have properties different from their constituent elements.
  • Mixtures can be separated by physical methods like filtration or evaporation.

Quick check

  1. Is air an element, compound, or mixture? Explain why.2 marks

2. Inside the Atom

Atoms are the building blocks of elements. They are made of three subatomic particles: protons, neutrons, and electrons. Protons (positive charge, +1) and neutrons (no charge, 0) are found in the center of the atom, in the nucleus. Electrons (negative charge, -1) orbit the nucleus in shells. The 'atomic number' (Z) of an element is the number of protons in its nucleus, and this number uniquely defines the element. The 'mass number' (A) is the total number of protons and neutrons in the nucleus. In a neutral atom, the number of electrons is equal to the number of protons, balancing the overall charge to zero.

Mass Number (A) = Number of Protons + Number of Neutrons

Number of Neutrons = Mass Number (A) - Atomic Number (Z)

In a neutral atom: Number of Protons = Number of Electrons

Key term

Atomic Number (Z): The number of protons in the nucleus of an atom, which determines the chemical properties of an element and its place in the periodic table.

Examiner insight

Examiners expect you to be able to use the atomic and mass numbers to find the composition of any atom. Be precise about the location and charge of each subatomic particle if asked.

Fun fact

If an atom were the size of a football stadium, the nucleus would be the size of a pea in the center, yet the nucleus contains almost all of the atom's mass.

Worked example 13 marks

A sodium atom has an atomic number of 11 and a mass number of 23. Determine the number of protons, neutrons, and electrons in a neutral sodium atom.

  1. 1

    The atomic number (Z) is the number of protons. So, number of protons = 11.

  2. 2

    In a neutral atom, the number of electrons equals the number of protons. So, number of electrons = 11.

  3. 3

    The mass number (A) is the sum of protons and neutrons. Number of neutrons = Mass Number - Atomic Number.

  4. 4

    Number of neutrons = 23 - 11 = 12.

  5. 5

    Final Answer: 11 protons, 12 neutrons, 11 electrons.

Recap

  • Atoms contain protons (+1), neutrons (0), and electrons (-1).
  • Protons and neutrons are in the nucleus; electrons are in shells.
  • The atomic number (Z) is the number of protons.
  • The mass number (A) is the number of protons plus neutrons.
  • For a neutral atom, protons equal electrons.

Quick check

  1. An atom has 6 protons and 7 neutrons. What is its atomic number and mass number?2 marks

4. Metals vs. Non-metals

Elements can be broadly classified into two main categories: metals and non-metals. They have very different sets of typical physical properties. Metals (like iron, copper, gold) are typically strong, shiny (lustrous), malleable (can be hammered into shape), ductile (can be drawn into wires), and are excellent conductors of heat and electricity. Most are solid at room temperature (mercury is a key exception). Non-metals (like sulfur, oxygen, chlorine) are typically dull, brittle when solid, and are poor conductors of heat and electricity (insulators). They exist as solids, liquids, or gases at room temperature.

Key term

Malleable: A physical property of metals that allows them to be hammered or pressed into different shapes without breaking or cracking.

Examiner insight

When comparing metals and non-metals, use comparative language like 'higher density' or 'better conductor' and refer to specific properties mentioned in the question.

Worked example 13 marks

An unknown element 'X' is a lustrous solid that is a very good conductor of electricity. Is element 'X' likely to be a metal or a non-metal? Justify your answer with two points.

  1. 1

    Conclusion: Element 'X' is likely to be a metal.

  2. 2

    Justification 1: The property of being 'lustrous' (shiny) is a typical characteristic of metals.

  3. 3

    Justification 2: Being a 'very good conductor of electricity' is another key physical property of metals, whereas non-metals are poor conductors.

Recap

  • Metals are typically lustrous, malleable, ductile, and good conductors.
  • Non-metals are typically dull, brittle, and poor conductors (insulators).
  • Most metals are solid at room temperature, while non-metals can be solids, liquids, or gases.
  • Metals generally have high melting points and densities.
  • Non-metals generally have low melting points and densities.

Quick check

  1. State the term used to describe the ability of a metal to be drawn into a wire.1 mark
  2. Is carbon (in the form of graphite) an exception to the conductivity rule for non-metals?1 mark

5. Alloys: Stronger by Design

A pure metal consists of atoms of the same size arranged in regular layers. These layers can slide over each other easily, which makes pure metals relatively soft. An 'alloy' is a mixture created by adding another element (often another metal or carbon) to a pure metal. This introduces atoms of a different size into the metal's structure. These different-sized atoms distort the regular layers, making it much more difficult for them to slide. As a result, alloys are harder, stronger, and often more resistant to corrosion than their parent metals. Examples include steel (iron and carbon), brass (copper and zinc), and bronze (copper and tin).

Key term

Alloy: A mixture of two or more elements, where at least one element is a metal, designed to have improved properties.

Common pitfall

Describing alloys as compounds. They are mixtures because the elements are physically mixed, not chemically bonded in a fixed ratio.

Fun fact

Aluminium is a light but soft metal. Alloying it with small amounts of copper, magnesium and manganese creates Duralumin, an alloy strong and light enough to be used for aircraft construction.

Worked example 14 marks

Explain, in terms of atomic structure, why the alloy brass is harder than pure copper.

  1. 1

    In pure copper, the atoms are all the same size and are arranged in regular layers.

  2. 2

    These layers can slide over each other easily when a force is applied, making pure copper relatively soft.

  3. 3

    Brass is an alloy of copper and zinc. The zinc atoms are a different size to the copper atoms.

  4. 4

    The different-sized zinc atoms disrupt the regular arrangement of the layers of copper atoms.

  5. 5

    This makes it more difficult for the layers to slide over each other, so a greater force is needed. This makes brass harder than pure copper.

Recap

  • Alloys are mixtures containing at least one metal.
  • Pure metals have a regular lattice structure of same-sized atoms.
  • Alloys have a distorted lattice due to different-sized atoms.
  • The distorted layers cannot slide easily, making alloys harder than pure metals.
  • Common alloys include steel, brass, and bronze.

Quick check

  1. What two elements are the main components of steel?1 mark

6. Visualising Matter: Particle Diagrams

Particle diagrams are simple drawings used to represent the arrangement of atoms and molecules in elements, compounds, and mixtures. A single circle represents one atom. For an 'element', all the circles are identical and separate (e.g., Argon, Ar). For a 'diatomic element', the circles are identical but joined in pairs (e.g., Oxygen, O₂). For a 'compound', different circles (representing different elements) are joined together in fixed groups or molecules (e.g., water, H₂O, would be one large circle joined to two smaller ones). For a 'mixture', different types of particles (which could be single atoms, diatomic molecules, or compound molecules) are shown in the same container but are not joined to each other.

Key term

Particle Model: A simplified representation used to show the arrangement and bonding of atoms and molecules in elements, compounds, and mixtures.

Examiner insight

Clarity is key. Examiners look for correctly drawn particles (atoms vs molecules) and correct arrangement (separated for mixtures, bonded for compounds). Use a key if your diagram uses different shapes or shading.

Worked example 13 marks

In the box provided, draw a particle diagram to represent a mixture of helium atoms (He) and fluorine molecules (F₂). Use a circle for a helium atom and a different style of circle for a fluorine atom.

  1. 1

    Draw several single, separate circles to represent individual helium atoms (e.g., ●).

  2. 2

    Draw several pairs of joined circles of a different style to represent diatomic fluorine molecules (e.g., ○-○).

  3. 3

    Ensure both types of particles are mixed randomly within the box and are not bonded to each other.

  4. 4

    The final diagram should show at least two of each particle type, randomly distributed, to clearly represent a mixture.

Recap

  • Single, identical circles represent an element like a noble gas.
  • Identical circles joined in pairs represent a diatomic element.
  • Different circles joined together represent a compound.
  • Different types of unjoined particles in the same container represent a mixture.
  • The key is to show whether particles are identical, different, joined, or separate.

Quick check

  1. How would you represent carbon monoxide (CO) in a particle diagram?1 mark

End-of-chapter exercise

Test yourself on the whole chapter. Work through these before moving on.

  1. Define 'element' and 'compound', giving one example of each.4 marks
  2. An atom of chlorine has an atomic number of 17 and a mass number of 35. State the number of protons, neutrons and electrons in a neutral atom of chlorine.3 marks
  3. Describe two differences in the typical physical properties of a metal, such as magnesium, and a non-metal, such as sulfur.4 marks
  4. Explain, using the particle model, why an alloy like steel is harder than pure iron.4 marks
  5. Draw a particle diagram in a box to represent a pure sample of a diatomic element.2 marks
  6. An element is in Group 2 and Period 4 of the periodic table. What is this element, and what type of ion would it form in a chemical reaction?2 marks
  7. A substance is a dull yellow solid that shatters when hit with a hammer and does not conduct electricity. Classify this substance as a metal or non-metal and justify your choice with two reasons.3 marks
  8. The element oxygen has atomic number 8. The element hydrogen has atomic number 1. They react to form water, H₂O. Is water an element, compound or mixture? Explain your answer.3 marks
  9. Why do elements in Group 17 (the halogens) have similar chemical properties to each other?2 marks
  10. A student is given a grey solid. They are told it is either pure zinc or the alloy brass (a mixture of copper and zinc). Describe a physical property you could measure to help identify the solid, and explain how it would help.3 marks

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